Most early reports on brush and branched polypeptides utilized conventional NCA polymerization techniques. The first graft polypeptides were published in 1956 by Sela et al.61 Using poly(l-lysine) or poly(d/l-ornithine) as a multifunctional initiator for the ROP of a number of different NCAs, these authors prepared a variety of graft polypeptides, which they termed multichain poly(amino acids) (eqn [18]).

Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences/Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture, Beijing 100081, China

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